Dozens of Americans and Canadians reported hearing an odd sound for twenty seconds to a minute at a time. Since DMSO can react with oxygen and form dimethyl sulfone, Grant began to wonder what other compounds might be formed when oxygen is added to the chemical. Manila is most commonly used for making file folders[1] and envelopes, called Manila folders and Manila envelopes, respectively. But if Ramirez had taken PCP, someone should have found some traces of the drug itself. A relatively unassuming bridge in Scotland holds a dark secret that has haunted the city of Glasgow, Scotland for years. At this point in the mystery, the only unusual thing were seeing is dimethyl sulfone, says Andresen. Ochoa and three others repeatedly administered electric shocks and drugs, but their efforts to stabilize Ramirez failed. On April 20, 1994ten weeks after her deathRamirez was buried at Olivewood Memorial Park in Riverside. Jamie founded Listverse due to an insatiable desire to share fascinating, obscure, and bizarre facts. An emergency room entrance. Though there was nothing unusual about her except for being too young, the incident that followed her admittance to the emergency room baffled the doctors and researchers. They maintain to this day that all the hikers died in an avalanche, but their quick sealing of the case has raised eyebrows and led to alternate theories. She fainted after handing the syringe to a medical resident, Julie Gorchynski, and was taken out of the room. Of the 20 types of symptoms reported by the staff, from the fainting to the convulsions to Gorchynskis hepatitis, only one nausea and vomiting is not a symptom of dimethyl sulfate exposure. Specifications. About 8:15p.m. on the evening of February 19, 1994, Ramirez, suffering from severe heart palpitations, was brought into the emergency department of Riverside General Hospital in Riverside, by paramedics. All That's Interesting is a Brooklyn-based digital publisher that seeks out stories that illuminate the past, present, and future. They stripped off her shirt and pressed padded electrodes against her chest; at that point several people saw an oily sheen covering Ramirezs body, and some noticed a fruity, garlicky odor that they thought was coming from her mouth. This was the gas that poisoned the emergency room staff. The hospital was evacuated except for a few people staying to help Ramirez, but she died forty-five minutes after she arrived at the hospital from complications of cancer. Others developed breathing problems and one nurse experienced paralysis and no one knew why. Her blood pressure continued to drop, and her pulse was growing fainter. Yet chemists have on several occasions discovered that seemingly impossible reactions turn out to be quite possible. During the mid-1960s a flurry of research showed it had remarkable healing powers, easing intractable pain and reducing anxiety. The warning is that the human body can be a place where bizarre and potentially deadly chemistry can occur. Andresen thinks some of the backlash was avoidable. [6] In Houck and Siegel's textbook, the authors state that, although some weaknesses exist, the postulated scenario is "the most scientific explanation to date" and that "beyond this theory, no credible explanation has ever been offered for the strange case of Gloria Ramirez. Ochoa lunged for Kane, caught her, and gently guided her limp body to the floor. A search of his house turned up a bizarre note taped to the back of his computer, which contained quotes from Freemason texts, lists of movie titles, and names of Hollywood figures. Five were hospitalized for the rest of the night. [2] Sold in gel form at hardware stores, it could also explain the greasy appearance of Ramirez's body. In real blood those crystals might have appeared manila-colored. Manila 2158-50 | Benjamin Moore Manila 2158-50 A peach-tinged beige that captures the iconic buff tone of manila paper. Known as the Oakville blobs, this transparent jelly fell in tiny droplets half the size of rice grains over a period of three weeks and reportedly sickened local people and animals with a flu-like illness. The team was supposed to come back by February 12th, and a search party of their classmates and teachers were sent out to look for them on the 20th. Residents speculated that it could be human waste dumped from passing planes, which could explain why it made people sick, but airlines quickly disputed this because plane waste is dyed blue. The incident was initially considered to be a case of mass hysteria. Appreciable amounts of it built up in the syringe, and some of it vaporized out of the blood. They emerged 90 minutes later with samples of blood and tissue along with air from the body bag and aluminum crate holding the body. The Livermore chemists envision a reaction which hasnt yet been observed in which some of the molecules of dimethyl sulfone in Ramirezs blood broke apart. Micozzi is a forensic pathologist who has helped investigate dozens of unusual deaths. The state report also angered some of the other emergency room staff, including Welch. The hazmat teams lack of suspects was not a relief, however, to the Riverside Coroners Office, whose pathologists were now left with the unnerving task of performing an autopsy on Ramirez without a clue as to what the body was harboring perhaps a fugitive pathogen, a toxic chemical, or nothing at all. Our colored particles are prepared by polymerizing styrene in oil soluble dye solution in styrene. Here are the details about the mystery of Gloria Ramirez and all the pandemonium that ensued. Perhaps unsurprisingly, people who had worked within two feet of Ramirez and had handled her intravenous lines had been at high risk. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. The coroners office has remained tight-lipped about the analysis it conducted in the days that followed. [2][3] A skeleton crew stayed behind to stabilize Ramirez. People are frustrated and want us to look at these cases from a chemistry point of view, says Andresen. When Ramirez collapsed (presumably from cancer-related kidney failure) and was put in an ambulance, the paramedics put an oxygen mask on her face. On March 25, after some preliminary discussions, the office officially requested Livermores help and shipped autopsy samples, on dry ice, to the lab. With this technique, you can layer a single . Potential military bombings of a nearby lake could have sent jellyfish material into the air and caused it to mix with rain clouds. Strange orange orbs were sighted by other nearby hikers around the time of the incident that some believe could have been a type of bomb. We found we could load it up in the Ringers solution to an appreciable extent without any sweat, says Grant. 10 pt. Colored Polystyrene Particles. The worlds only Antarctic murder mystery remains unsolved. After Welch collapsed, several other staff members began to say they felt ill, and hospital administrators declared an internal emergency. The ropes were made from abac or Musa textilis, which is grown in the Philippines;[3] hence the association with Manila, its capital city. Ive gotten messages on my answering machine from chemists who say its an impossible conclusion, says Andresen. Finally, the electric shocks during defibrillation could have converted DMSO2 to DMSO4, exposure to which could have caused the symptoms among those who were in the vicinity. Matching Colors Simply White 2143-70 Add to Cart Shopping List Facebook Watch is the place to enjoy videos and shows together. Grant, "Response to Letters to the Editor Concerning the Riverside 'Mystery Fumes' Incident Analysis", https://en.wikipedia.org/w/index.php?title=Death_of_Gloria_Ramirez&oldid=1124288808, Articles needing more detailed references, Creative Commons Attribution-ShareAlike License 3.0. He and his fiance were both spending the winter at the Amundsen-Scott South Pole Station with forty-eight other crewmates. The Livermore team was able to cull details about the symptoms of dimethyl sulfate exposure from the reference book, as well as from a safety sheet that accompanies any dimethyl sulfate purchased by industry. Multiple calls to the fire department did not get through. The solution became supersaturated, and dimethyl sulfone began to form beautiful white crystals, says Whipple, who did the experiment with Grant. When it became clear to them that she wasnt responding, they tried to defibrillate her. Her blood also alarmingly smelled like ammonia. As the syringe filled, Kane noticed a chemical smell to the blood. [2], The county health department called in California's Department of Health and Human Services, which put two scientists, Drs. There was not yet a sufficient amount of nerve gas to harm the paramedics. While treating Ramirez, several hospital workers fainted and others experienced symptoms such as shortness of breath and muscle spasms. It took six months before the body could be removed and autopsied, when it was determined that Marks had died of menthol poisoning. The shattering pattern, unique to every substance, is called a mass spectrum. But in Ramirezs blood and tissues there was a hefty concentration of tens of micrograms per milliliter, about three times higher than the codeine in the samples. The American government stated that they believed Cuba was responsible for the events. (A liter of liquid dimethyl sulfate sells for around $32.) It is manufactured as an industrial solvent, but it is also sometimes produced naturally in our bodies from amino acids that contain sulfur. But other factors that correlated with severe symptoms did not appear to match a scenario in which fumes had been released: the survey found that those afflicted tended to be women rather than men, and they all had normal blood tests after the exposure. Menu for Verde Taqueria in Brookhaven, GA. TAQUERIADELSOL.COM GIFT CARDS AVAILABLE! She had been admitted to the emergency department while suffering from late-stage cervical cancer. At this point, Kane fainted and was removed from the room. Police turned suspicion onto her husband, who they believed may have attacked her with a fireplace poker. Ramirezs seemingly average life took its unusual turn on Feb. 19, 1994, when she was taken to General Hospital in Riverside, Calif. after she experienced a rapid heart rate, a drop in blood pressure, and was unable to form coherent sentences. Other scientists dont see a match between the symptoms of the hospital staff and some of the symptoms of industrial workers who have been accidentally exposed to dimethyl sulfate. At 1:00 a.m., she heard an object hit the roof and roll but she went back to sleep. Six days later, the search party found the campsite with nine sets of footprints and two bodies nearby under a pine tree. But the strangest theory is a supernatural idea. The tan-ish color of the envelope is known as Buff or un-dyed. The drop, containing hundreds of chemicals, was vaporized and shunted into a chromatography column, where it was slowly heated to 570 degrees. Shop Now LRV 68.26 Collection Color Preview Get your own digital color dollop of Manila 2158-50 Create My Dollop Lighting Screen colors may differ. (based on the use of quantum dots) detecting enrofloxacin. [5], The possible chemical explanation for this incident by Patrick M. Grant of the Livermore Forensic Science Center is beginning to appear in basic forensic science textbooks. Translation Context Grammar Check Synonyms Conjugation. The nurse who drew the blood quickly fainted, and soon two other people in the room passed out. But in the past decade, as the production of nuclear weapons has tapered off, Livermore and its fellow labs have attempted to find an identity better suited to a post- cold war world. In chemistry little changes can sometimes lead to big results. They also noticed an oily sheen on her chest and a fruity, garlic-like odor which they thought was coming from her mouth. We just wanted the coroners offices opinion, and they took it and said, This is the answer. It caught us way off guard. Then when I woke up, I couldnt control the movements of my limbs. This theory has been endorsed by the Riverside Coroner's Office and published in the journal Forensic Science International. Whatever the true reason, Overtoun Bridge now has signs installed warning owners to keep their pets on leashes during their walks. The medical staff hovering over Ramirez injected her with a host of fast-acting drugs that were part of the standard protocol for her condition: Valium, Versed, and Ativan to sedate her, and agents such as lidocaine and Bretylium to quell her aberrant heartbeat. He was discouraged. No one clue gives a perfect fit to explain a death, but when all the clues are added up, you get a pattern. file security - colored manila folders stock illustrations. And people still go nuts. But other factors that correlated with severe symptoms didnt seem to match a scenario in which fumes had been released: the survey found that those afflicted tended to be women rather than men, as well as people who had skipped dinner that evening rather than those who had a full stomach. However, a shopkeeper saw her the day of her disappearance and reported that she seemed happy and calm, picking up souvenirs for her family. Ramirez was only 31-years-old and in the late stages of cervical cancer which was thought to have caused her sudden deterioration. The team would also check for any gases that may have vented off the samples into the headspace, the pocket of air separating the samples from the tops of their containers. If the children were kidnapped, they may not have come forward to protect the rest of their family from harm. This is where we were afraid we might find a showstopper that would kill the theory, says Grant. She was extremely confused and was suffering from tachycardia and CheyneStokes respiration. But Lams case is one of the most bizarre. How Effective Are Colonoscopies at Detecting Colon Cancer? More recently new woodpulp has often been replaced with a high proportion of recycled fibers. [3] Oxygen administered by the paramedics would have combined with the DMSO to form dimethyl sulfone (DMSO2). In 2016, diplomatic staff in Cuba began to experience a strange illness. It would seem to me that it would take a hell of a lot of DMSO, but in that stage of fighting for her life, Ramirez may have really overloaded on it, he says. However, the unique environment also means that the United States, New Zealand, and Australia all share jurisdiction, which prevented significant investigation from taking place. They searched for any of a host of noxious chemicals, including hydrogen sulfide (also known as sewer gas), an insidious poison that smells like rotten eggs and at high concentrations can kill a person after one or two whiffs, and phosgene, a gas with a dual identity on the one hand, a law-abiding ingredient used in the preparation of many organic chemicals, and on the other a terrible weapon for chemical warfare that tears open capillaries in the lungs, drowning its victims in blood. But given its potential side effects, its a dangerous remedy because in its readily available hardware- store grease-cutting form, its 99 percent pure. On May 24th, 2006, 32-year-old financial writer Rey Rivera was found dead in the conference room of the Belvedere Hotel in Baltimore, Maryland. Ignoring the red herrings, Andresen found a few interesting anomalies. Fourteen months after the incident, the Riverside cases legacy remains peculiar and shadowy. Broken down by the liver, dimethyl sulfone has a half-life in the body of less than three days, so healthy people never have measurable amounts in their system. Her heart was beating too rapidly to allow its chambers to fill before they pumped, so her blood pressure was plummeting. Grant was a bit hesitant. However, Osorio and Waller did not rule out the possibility that some substance poisoned emergency room staff who had worked directly over Ramirez. If theres one place where you dont want to have a medical emergency, its the remote tundra of the South Pole. It contained a photo with a strong resemblance to him, but the lead went nowhere. On the same page of the index he had been reading, he found the answer: dimethyl sulfate. We had a meeting on the very last day of the month to determine our exact game plan, says Brian Andresen, the centers director. Im pretty skeptical, says Hans Reich, an organic chemist at the University of Wisconsin at Madison. Her blood also alarmingly smelled like ammonia. To help lure him back to the case, she sent him a copy of a scrapbook of material she had accumulated, including news stories, the Riverside coroners report, legal briefs, and toxicology reports. Five workers required hospitalization, one of whom remained in an intensive care unit for two weeks. Shortly thereafter, Gorchynski began to feel nauseated. Grant was more familiar with dmso because, he says, Id used dmso in a former life as an athlete. When youre exposed to dimethyl sulfate vapors, the first thing that happens is it makes you start to cry. There are 3 types of particles that are colorizeable, however it is not so obvious how this works. The puzzle is that if the Livermore investigators are wrong, then what did happen in the Riverside emergency room on February 19, 1994? Taking no chances, they put on airtight moon suits and disappeared into a sealed examining chamber to work on the body. The standard model is the name given in the 1970s to a theory of fundamental particles and how they interact. At 8:50p.m., after 45 minutes of CPR and defibrillation, Ramirez was pronounced dead from kidney failure related to her cancer. A second investigation from Livermore National Laboratory came to a different conclusion. The town reportedly jumped on this theory, selling a vodka gelatin jellyfish drink at the local bar. She was sedated and then defibrillated by doctors, who noticed that her body was covered in an oily sheen. At 8:50 Ochoa pronounced her dead. Maureen Welch, a respiratory therapist who was assisting in the trauma room, was the third to pass out. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. This page was last edited on 28 November 2022, at 05:44. Im a nuclear chemist, and my organic chemistry knowledge truthfully is minuscule, he says. [2][3] The Livermore scientists theorized that the DMSO in Ramirez's system might have built up owing to urinary blockage caused by her kidney failure. Using a standardized questionnaire, Osorio and Waller found that the people who had developed severe symptoms, such as loss of consciousness, shortness of breath, and muscle spasms, tended to have certain things in common. The 10 Weirdest People In History, From The Toxic Lady To The Hopeless Romantic Gravedigger. In court, three experts backed the possibility that an owl had attacked her and caused a deadly fall down the stairs. Registered nurse Susan Kane drew blood from Ramirez's arm and noticed an ammonia-like smell coming from the tube. One of the harshest critics of the Livermore theory is a scientist who did much of the clinical research on DMSO in the early 1960s. The long-term effects of these kinds of devices remain unknown. Kane passed the blood sample to the attending doctor, who agreed that the blood smelled like ammonia, before giving the vial to a medical student named Julie Gorchynski, who noticed strange manila-colored particles in the sample. He was last seen eight days earlier when a houseguest watched Rivera take a phone call and run frantically from his house. [4] The Livermore scientists postulated on The New Detectives that the change in temperature of the blood drawn, from the 98.6F (37C) of Ramirez's body to the 64 F (18C) of the emergency department, may have contributed to its conversion from DMSO2 into DMSO4. Andresen measured their concentrations and then piped the vapors into the mass spectrometer chamber, which fires electrons at the chemicals. It takes a really damn potent toxin to do all that, says Sheldon Wagner, a clinical toxicologist at Oregon State University. Outside, in the parking lot, hospital staff were treating patients and ill colleagues under the dull orange glow of sulfur lamps. One was an unidentified amine, a derivative of ammonia, that may have contributed to the ammonia-like smell noted in the emergency room. Andresen laid out a paper with the gas chromatography-mass spectrometry results, a graph with spikes similar to earthquake readings on a seismograph, and pointed at the dimethyl sulfone peak. Its like that silliness with cold fusion, except this has the potential to hurt people, he says. Andresen recalls some anxious questioning by the coroners office in hopes of finding a smoking gun, but he insisted that it appeared Ramirez had simply taken a lot of codeine and Tylenol, which in large, sustained doses can damage the liver. Following that, several other people, including staff, started saying they felt ill and the staff was ordered to evacuate the emergency room to the hospitals parking lot. Andresens team is going to conduct more experiments and check Ramirezs blood again; soon they hope to turn their preliminary report into a paper they will submit to a refereed forensic journal. He also highlighted the findings that had intrigued him: the amine that might have caused the ammonia-like odor, the nicotinamide, and the dimethyl sulfone. It took the fire department hours to respond and by then the house had burned completely to ash. The small, brightly colored particlesoften stick to clothing, skin, and furniture, and can be a hassle to remove. someone shouted. Nurses removed Ramirezs shirt and saw a mysterious oily sheen on her skin and her mouth was emitting a fruity, garlicky smell. This WWII Shipwreck Is Pouring Pollutants Into The North Sea. The Mysterious Disappearance Of The Sri Lankan Handball Team. CD Bioparticles provide a wide range of uniform and monodisperse colored polystyrene particles. "[7], Grant's conclusions and speculations about the incident were evaluated by professional forensic scientists, chemists, and toxicologists, passed peer review in an accredited, refereed journal, and were published by Forensic Science International. He tried to pull his truck around to climb to the second floor, but it would not start. Shortly after that, three of the medics began feeling sick and fainted one after the other. Colored particles are bound together by the appropriately named gluons. Yuri Yudin stated that he believed there was an explosion, possibly from a weapons test, and cover-up by the Soviet military. Each of the emitters has its own texture emission attributes, so you can apply a different texture (or color) to each group of particles even though each emitter emits the same nParticle object. There were multiple reports from locals that they had spotted the Sodder children in the years following the fire and a letter came to the family in 1968 claiming to be from a surviving son. Next Andresen analyzed the samples using a high-powered tool known as a computer-guided combined gas chromatograph-mass spectrometer. Now the Livermore team needed to figure out the next step: how the relatively harmless dimethyl sulfone could have been converted to the extraordinarily harmful dimethyl sulfate. Dimethyl sulfate doesnt vaporize easily the Merck Index lists its boiling point as 370 degrees. In addition, they pointed out, neither paramedic who had treated Ramirez in the ambulance became ill despite the close quarters and their having touched her skin and some of her blood after starting an intravenous line. They also noticed strange manila-colored particles floating in the blood. Trace levels of radiation were discovered in the campsite and a scrap of cloth from a military jacket was also found at the scene. [2], She passed the tube to Julie Gorchynski, a medical resident, who noticed manila-colored particles floating in the blood. Lams family asked the police to look for her after she failed to contact them during her trip. The Livermore scientists had been working on the case for free as a public service, after hours and on the weekends. Fiber patch and drilled hole for extra reinforcment. I just tell them the dimethyl sulfate theory is a chemical impossibility, says Jacob. The Riverside Coroner's Office hailed Livermore's DMSO conclusion as the probable cause of the hospital workers' symptoms, while her family disagreed. In other words, theyd been felled by stress and anxiety. This, however, has not been confirmed. The crystals of dimethyl sulfone turned into dimethyl sulfate as well and vanished from sight. Ana Maria Osorio and Kirsten Waller, on the case. Rather, the Livermore team thought the more likely event was that Ramirez had rubbed DMSO on herself to relieve the pain from her cancer. So the products they use are superclean and sterilized but covered in chemicals. Grant didnt get to Welchs file until a few days later when he was on a flight to a business meeting in Washington, D.C. The researchers could think of two scenarios that would explain how Ramirez had been exposed to DMSO. [citation needed] Because the paper is generally inexpensive, it is commonly given to children for making art. They took a blood sample and saw manila-colored particles floating in it. Welch called Andresen at Livermore and implored him to take another look. Boxed in groups of 1,000. However, a former hotel employee endorsed the theory and said that helicopters were known to fly low over the hotel, despite the airspace rules. She was taking shallow, rapid breaths. In the RGB color model #e7c9a9 is comprised of 90.59% red, 78.82% green and 66.27% blue. Marc Micozzi, director of the National Museum of Health and Medicine in Washington, D.C., is one. One reference was particularly enlightening, if grisly a classified Department of Defense document, issued in 1987, called the Reference Book on Chemical Warfare Information. In her case the avascular necrosis attacked her knees, restricting her to crutches for months. It was later discovered that she was being treated for bipolar disorder, but had it under control for several years. To the relief of hospital administrators, the hazmat crew detected none of these chemicals in the emergency room. Acoustic or sonic weapons have been in development since at least the 1990s and certain types have been used around the world to disperse crowds and protesters. Shortly after, everyone standing near the dying woman was starting to feel sick and nauseous. The electrons shatter the molecules into all types of pieces, says Andresen. Overtoun Bridge is known for being a place where dogs leap to their deaths, shocking local residents and drawing international media attention. To obtain blood for analysis, a registered nurse named Susan Kane swabbed Ramirezs right arm with rubbing alcohol, inserted a catheter, and attached a syringe. Dubbed the toxic lady, the hospital staff who were exposed to her body became ill and even had to be hospitalized. If the owl did do it, then he got away with it, as Michael Peterson served eight years in prison for his wifes death. in /home1/neuxs/public_html/www.biggervisionmusic.com/wp-content . Complaining that she was lightheaded, she left the trauma room and sat at a nurse's desk. The hotel itself has had a spooky reputation for decades as the site of several suicides and connections to several murders. One of the most interesting theories is that Rivera was dropped through the roof of the hotel by a helicopter, possibly because of his work cleaning up the public image of his childhood friend Porter Stansberry. Kane flailed her arms and kicked, and her face still burned. When they cooled a vial of this Ringers solution crammed with dimethyl sulfone to room temperature (about 70 degrees), they were greeted by a good sign. Catch her! Questions were immediately raised over how she made it to the locked rooftop and how she replaced the heavy lid from inside. someone shouted. The county health department called in Californias Department of Health and Human Services, which put two of its top scientists on the case, Doctors Ana Maria Osorio and Kirsten Waller. Sealed examining chamber to work on the same page of the blood turn... Bag and aluminum crate holding the body went nowhere herrings, Andresen found few... 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